Crystalline plasticity in isotactic polypropylene below and above the glass transition temperature
نویسندگان
چکیده
منابع مشابه
Physical stability of drugs after storage above and below the glass transition temperature: Relationship to glass-forming ability
Amorphous materials are inherently unstable and tend to crystallize upon storage. In this study, we investigated the extent to which the physical stability and inherent crystallization tendency of drugs are related to their glass-forming ability (GFA), the glass transition temperature (Tg) and thermodynamic factors. Differential scanning calorimetry was used to produce the amorphous state of 52...
متن کاملPrimary Crystal Nucleation and Growth Regime Transition in Isotactic Polypropylene
We studied nucleation and crystal growth in two polypropylene samples by analyzing the number of spherulites, their size, and shape for various treatments in a hot-stage microscope. The consistency of nucleation and growth data were tested by using overall crystallization experiments and the Jonhson–Mehl–Avrami–Kolmogorov Q1 equation. In isothermal conditions, for temperatures, TC, varying betw...
متن کاملParticle dynamics in colloidal suspensions above and below the glass-liquid re-entrance transition
We study colloidal particle dynamics of a model glass system using confocal and fluorescence microscopy as the sample evolves from a hard-sphere glass to a liquid with attractive interparticle interactions. The transition from hard-sphere glass to attractive liquid is induced by short-range depletion forces. The development of liquid-like structure is indicated by particle dynamics. We identify...
متن کاملSelf-Organized Criticality Below The Glass Transition
– We obtain evidence that the dynamics of glassy systems below the glass transition is characterized by self-organized criticality. Using molecular-dynamics simulations of a model glass-former we identify clusters of cooperatively jumping particles. We find string-like clusters whose size is power-law-distributed not only close to Tc but for all temperatures below Tc, indicating self-organized ...
متن کاملDynamical heterogeneities below the glass transition
Related Articles Transport coefficients of the TIP4P-2005 water model J. Chem. Phys. 136, 044507 (2012) Monte Carlo study of four dimensional binary hard hypersphere mixtures J. Chem. Phys. 136, 014506 (2012) Energy relaxation of intermolecular motions in supercooled water and ice: A molecular dynamics study J. Chem. Phys. 135, 244511 (2011) The role of the isothermal bulk modulus in the molecu...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Express Polymer Letters
سال: 2015
ISSN: 1788-618X
DOI: 10.3144/expresspolymlett.2015.81